The material is a bit scratchy. it's the same as a pocket square that has a tag that says 100% silk, but I have a real silk handkerchief, I have some satin pillowcases and some polyester shirts. So I can tell just by touch that it's a mix of polyester and satin with something else that gives it stiffness. I have a 16 inch neck so I'm between medium and large but they can't be tied properly because the skinny part is shorter than it should be.
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