After trying to remove the smell of cat pee from grout and baseboards with all sorts of substances designed to help - no! β I tried Angry Orange. Relief! I've treated several times for urine getting into the joints and gap between the baseboard and the wall (this happened before I realized that a cat doesn't always crouch down to urinate and before I installed the blockages), and it worked great! No smell of cat urine! I don't know how it works on carpet, but it works very well on tile and baseboards.
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