I don't know what the material is or if "rust" is the right word for what happened. I bought this tube because I needed a copper tube for heat transfer (non-food grade) for my little hobby project. 24 hours (in air) after unpacking this hose I flushed the line with water and noticed a black residue coming out of the back. I looked closely and saw that black spots had formed on the pipe. I couldn't use this without risking damaging my flow pumps so I put it in a heap to throw away. A week later, the black pockmarks turned into whole black sections of the whistle. For the brake line I would recommend a hard pass for this product. Black deposits can easily clog nozzles or damage pumps. Blackened areas of the hose pose a leak/rupture hazard which is simply not necessary and definitely not what you need for a critical system like brakes.
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