I've used them with 10 year old PSUs and 1 year old PSUs and haven't had any problems with matching or over current, burning laptops or anything horrible. If it's not clear from the description, they take the larger barrel tips and shrink them down to narrower barrel tips so you can use old PSUs with newer laptops (they also make the cable about a foot longer). I would guess the only downside I see is that older power adapters may not have the power to charge large laptop batteries meaning it may take longer to charge. But it's a great way to repurpose old power supplies.
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