I LOVE these bottles. They are cute, durable and tiny. I bought these to use with hand sanitizer spray in a 1 gallon container. I have used them for trips in and around. A house. I usually toss them in a small plastic bag before throwing them in my purse. So I don't know if the cap pops out on impact, but they seem pretty sturdy to me. It takes some effort to press the spray mechanism, which I like because it doesn't make a mess.
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