I wear them when cycling on wet roads. There are ventilation holes on the bottom of my cycling shoes. So if I walk through a puddle or drive on a very wet road, water gets into the shoes. In such conditions, my feet stay dry. The socks are breathable so I don't feel like my feet are getting wet from the inside. In heavy rain, socks will eventually get wet. On my most recent 65-mile ride in the rain, my feet stayed dry for several hours, but my socks got wet.
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