These napkins are made of comfortable, dense (enough for one napkin) cotton. They wrinkle when you wash them and as several other reviewers have pointed out, they don't come out of the wash square. However, it took me about a minute to iron them and use an iron to fold them back into perfect squares. I think this is exactly what you need if you want a 100% cotton doily. If you want wrinkle resistant, poly or a poly blend may be your best bet.
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